Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate

The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol­ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro­form solvate. The solvent mol­ecule is disordered about a site of symm...

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Detalles Bibliográficos
Autores principales: Wong, Richard Chee Seng, Ooi, Mei Lee, Sakurai, Hidehiro, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961173/
https://www.ncbi.nlm.nih.gov/pubmed/21202381
http://dx.doi.org/10.1107/S1600536808010817
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author Wong, Richard Chee Seng
Ooi, Mei Lee
Sakurai, Hidehiro
Ng, Seik Weng
author_facet Wong, Richard Chee Seng
Ooi, Mei Lee
Sakurai, Hidehiro
Ng, Seik Weng
author_sort Wong, Richard Chee Seng
collection PubMed
description The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol­ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro­form solvate. The solvent mol­ecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry.
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spelling pubmed-29611732010-12-30 Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate Wong, Richard Chee Seng Ooi, Mei Lee Sakurai, Hidehiro Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol­ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro­form solvate. The solvent mol­ecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961173/ /pubmed/21202381 http://dx.doi.org/10.1107/S1600536808010817 Text en © Wong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wong, Richard Chee Seng
Ooi, Mei Lee
Sakurai, Hidehiro
Ng, Seik Weng
Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title_full Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title_fullStr Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title_full_unstemmed Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title_short Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
title_sort tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961173/
https://www.ncbi.nlm.nih.gov/pubmed/21202381
http://dx.doi.org/10.1107/S1600536808010817
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