6-(2-Methoxy­benzyl­amino)purine

The title compound, C(13)H(13)N(5)O, consists of discrete mol­ecules connected by N—H⋯N hydrogen bonds to form infinite chains, with N⋯N separations of 3.0379 (15) and 2.8853 (15) Å. The benzene and purine ring systems make a dihedral angle of 77.58 (3)°. The crystal structure is further stabilized...

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Autores principales: Trávníček, Zdeněk, Matiková-Maľarová, Miroslava, Mikulík, Jiří
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961176/
https://www.ncbi.nlm.nih.gov/pubmed/21202313
http://dx.doi.org/10.1107/S1600536808009203
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author Trávníček, Zdeněk
Matiková-Maľarová, Miroslava
Mikulík, Jiří
author_facet Trávníček, Zdeněk
Matiková-Maľarová, Miroslava
Mikulík, Jiří
author_sort Trávníček, Zdeněk
collection PubMed
description The title compound, C(13)H(13)N(5)O, consists of discrete mol­ecules connected by N—H⋯N hydrogen bonds to form infinite chains, with N⋯N separations of 3.0379 (15) and 2.8853 (15) Å. The benzene and purine ring systems make a dihedral angle of 77.58 (3)°. The crystal structure is further stabilized by intra­molecular N⋯O inter­actions [2.9541 (12) Å] and inter­molecular C—H⋯C and C⋯C contacts [3.304 (2), 3.368 (2), 3.667 (2), 3.618 (2) and 3.512 (2) Å] which arrange the mol­ecules into graphite-like layers. The inter­layer separations are 3.248 and 3.256 Å.
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spelling pubmed-29611762010-12-30 6-(2-Methoxy­benzyl­amino)purine Trávníček, Zdeněk Matiková-Maľarová, Miroslava Mikulík, Jiří Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(13)N(5)O, consists of discrete mol­ecules connected by N—H⋯N hydrogen bonds to form infinite chains, with N⋯N separations of 3.0379 (15) and 2.8853 (15) Å. The benzene and purine ring systems make a dihedral angle of 77.58 (3)°. The crystal structure is further stabilized by intra­molecular N⋯O inter­actions [2.9541 (12) Å] and inter­molecular C—H⋯C and C⋯C contacts [3.304 (2), 3.368 (2), 3.667 (2), 3.618 (2) and 3.512 (2) Å] which arrange the mol­ecules into graphite-like layers. The inter­layer separations are 3.248 and 3.256 Å. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961176/ /pubmed/21202313 http://dx.doi.org/10.1107/S1600536808009203 Text en © Trávníček et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trávníček, Zdeněk
Matiková-Maľarová, Miroslava
Mikulík, Jiří
6-(2-Methoxy­benzyl­amino)purine
title 6-(2-Methoxy­benzyl­amino)purine
title_full 6-(2-Methoxy­benzyl­amino)purine
title_fullStr 6-(2-Methoxy­benzyl­amino)purine
title_full_unstemmed 6-(2-Methoxy­benzyl­amino)purine
title_short 6-(2-Methoxy­benzyl­amino)purine
title_sort 6-(2-methoxy­benzyl­amino)purine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961176/
https://www.ncbi.nlm.nih.gov/pubmed/21202313
http://dx.doi.org/10.1107/S1600536808009203
work_keys_str_mv AT travnicekzdenek 62methoxybenzylaminopurine
AT matikovamalarovamiroslava 62methoxybenzylaminopurine
AT mikulikjiri 62methoxybenzylaminopurine

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