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5-Bromo-2-methyl-3-phenylsulfonyl-1-benzofuran
The title compound, C(15)H(11)BrO(3)S, was prepared by the oxidation of 5-bromo-2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 78.99 (8)° with the plane of the benzofuran fragment. The crystal structure is stabilized by C—H⋯π inte...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961177/ https://www.ncbi.nlm.nih.gov/pubmed/21202285 http://dx.doi.org/10.1107/S1600536808008489 |
Sumario: | The title compound, C(15)H(11)BrO(3)S, was prepared by the oxidation of 5-bromo-2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 78.99 (8)° with the plane of the benzofuran fragment. The crystal structure is stabilized by C—H⋯π interactions between a benzene H atom of the benzofuran unit and the phenyl ring of the phenylsulfonyl substituent from a neighbouring molecule. In addition, the crystal structure exhibits intra- and intermolecular C—H⋯O interactions. |
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