Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate

The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal­lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter­molecular O—H⋯O hydr...

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Detalles Bibliográficos
Autores principales: Guo, Yujing, Li, Lianzhi, Liu, Yan, Dong, Jianfang, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961190/
https://www.ncbi.nlm.nih.gov/pubmed/21202214
http://dx.doi.org/10.1107/S1600536808009872
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author Guo, Yujing
Li, Lianzhi
Liu, Yan
Dong, Jianfang
Wang, Daqi
author_facet Guo, Yujing
Li, Lianzhi
Liu, Yan
Dong, Jianfang
Wang, Daqi
author_sort Guo, Yujing
collection PubMed
description The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal­lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex and water mol­ecules to form a three-dimensional network. The O atom of one of the unique hydroxy­methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21.
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spelling pubmed-29611902010-12-30 Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate Guo, Yujing Li, Lianzhi Liu, Yan Dong, Jianfang Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal­lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex and water mol­ecules to form a three-dimensional network. The O atom of one of the unique hydroxy­methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961190/ /pubmed/21202214 http://dx.doi.org/10.1107/S1600536808009872 Text en © Guo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Yujing
Li, Lianzhi
Liu, Yan
Dong, Jianfang
Wang, Daqi
Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title_full Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title_fullStr Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title_full_unstemmed Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title_short Tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(II) tetra­hydrate
title_sort tetra­kis(μ(3)-2-{[1,1-bis­(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-6-methoxy­phenol­ato)tetra­nickel(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961190/
https://www.ncbi.nlm.nih.gov/pubmed/21202214
http://dx.doi.org/10.1107/S1600536808009872
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AT lilianzhi tetrakism3211bishydroxymethyl2oxidoethyliminomethyl6methoxyphenolatotetranickeliitetrahydrate
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AT dongjianfang tetrakism3211bishydroxymethyl2oxidoethyliminomethyl6methoxyphenolatotetranickeliitetrahydrate
AT wangdaqi tetrakism3211bishydroxymethyl2oxidoethyliminomethyl6methoxyphenolatotetranickeliitetrahydrate

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