Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}

In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg—I bond [2.6895 (7) Å], one Hg—C bond and two asymmetric bridging Hg—I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol­ecule has a crystallographic inversion centre at the ce...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Karami, Kazem, Yalçın, Şerife Pınar, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961191/
https://www.ncbi.nlm.nih.gov/pubmed/21202170
http://dx.doi.org/10.1107/S1600536808008611
Descripción
Sumario:In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg—I bond [2.6895 (7) Å], one Hg—C bond and two asymmetric bridging Hg—I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol­ecule has a crystallographic inversion centre at the centroid of the four-membered ring formed by the two Hg atoms and two I atoms. The crystal packing is stabilized by C—H⋯O hydrogen bonds.

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