Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}

In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg—I bond [2.6895 (7) Å], one Hg—C bond and two asymmetric bridging Hg—I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol­ecule has a crystallographic inversion centre at the ce...

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Autores principales: Akkurt, Mehmet, Karami, Kazem, Yalçın, Şerife Pınar, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961191/
https://www.ncbi.nlm.nih.gov/pubmed/21202170
http://dx.doi.org/10.1107/S1600536808008611
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author Akkurt, Mehmet
Karami, Kazem
Yalçın, Şerife Pınar
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Karami, Kazem
Yalçın, Şerife Pınar
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg—I bond [2.6895 (7) Å], one Hg—C bond and two asymmetric bridging Hg—I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol­ecule has a crystallographic inversion centre at the centroid of the four-membered ring formed by the two Hg atoms and two I atoms. The crystal packing is stabilized by C—H⋯O hydrogen bonds.
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spelling pubmed-29611912010-12-30 Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)} Akkurt, Mehmet Karami, Kazem Yalçın, Şerife Pınar Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg—I bond [2.6895 (7) Å], one Hg—C bond and two asymmetric bridging Hg—I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol­ecule has a crystallographic inversion centre at the centroid of the four-membered ring formed by the two Hg atoms and two I atoms. The crystal packing is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961191/ /pubmed/21202170 http://dx.doi.org/10.1107/S1600536808008611 Text en © Akkurt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akkurt, Mehmet
Karami, Kazem
Yalçın, Şerife Pınar
Büyükgüngör, Orhan
Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title_full Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title_fullStr Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title_full_unstemmed Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title_short Di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(II)}
title_sort di-μ-iodido-bis­{[(4-fluoro­benzoyl­methyl­ene)triphenyl-λ(5)-phospho­rane]iodido­mercury(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961191/
https://www.ncbi.nlm.nih.gov/pubmed/21202170
http://dx.doi.org/10.1107/S1600536808008611
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