3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K

In the title compound, C(15)H(20)ClNO(3), the seven-membered ring adopts a distorted boat–sofa conformation; the methyl­ene C atoms of this ring are coplanar with the benzene ring. Both meth­oxy groups are almost coplanar with the attached benzene ring [C—C—O—C = 6.5 (2) and −13.5 (3)°]. An intra­mo...

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Autor principal: Cheng, Xiang-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961196/
https://www.ncbi.nlm.nih.gov/pubmed/21202294
http://dx.doi.org/10.1107/S1600536808008787
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author Cheng, Xiang-Wei
author_facet Cheng, Xiang-Wei
author_sort Cheng, Xiang-Wei
collection PubMed
description In the title compound, C(15)H(20)ClNO(3), the seven-membered ring adopts a distorted boat–sofa conformation; the methyl­ene C atoms of this ring are coplanar with the benzene ring. Both meth­oxy groups are almost coplanar with the attached benzene ring [C—C—O—C = 6.5 (2) and −13.5 (3)°]. An intra­molecular C—H⋯O hydrogen bond is observed in the mol­ecular structure. In the crystal structure, a C—H⋯π inter­action involving the benzene ring is observed.
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spelling pubmed-29611962010-12-30 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K Cheng, Xiang-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(20)ClNO(3), the seven-membered ring adopts a distorted boat–sofa conformation; the methyl­ene C atoms of this ring are coplanar with the benzene ring. Both meth­oxy groups are almost coplanar with the attached benzene ring [C—C—O—C = 6.5 (2) and −13.5 (3)°]. An intra­molecular C—H⋯O hydrogen bond is observed in the mol­ecular structure. In the crystal structure, a C—H⋯π inter­action involving the benzene ring is observed. International Union of Crystallography 2008-04-04 /pmc/articles/PMC2961196/ /pubmed/21202294 http://dx.doi.org/10.1107/S1600536808008787 Text en © Xiang-Wei Cheng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Xiang-Wei
3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title_full 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title_fullStr 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title_full_unstemmed 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title_short 3-(3-Chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1H-3-benzazepin-2-one at 125 K
title_sort 3-(3-chloro­prop­yl)-7,8-dimeth­oxy-2,3,4,5-tetra­hydro-1h-3-benzazepin-2-one at 125 k
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961196/
https://www.ncbi.nlm.nih.gov/pubmed/21202294
http://dx.doi.org/10.1107/S1600536808008787
work_keys_str_mv AT chengxiangwei 33chloropropyl78dimethoxy2345tetrahydro1h3benzazepin2oneat125k

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