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Poly[(μ(3)-nicotinato-κ(3) O:O′:N)(μ(2)-nicotinato-κ(3) O,O′:N)iron(II)]
In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O′-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961197/ https://www.ncbi.nlm.nih.gov/pubmed/21202251 http://dx.doi.org/10.1107/S1600536808011045 |
| _version_ | 1782188924867706880 |
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| author | Ng, Seik Weng |
| author_facet | Ng, Seik Weng |
| author_sort | Ng, Seik Weng |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O′-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octahedral coordination geometry but one of the Fe—O bonds is somewhat long [2.522 (2) Å]. |
| format | Text |
| id | pubmed-2961197 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29611972010-12-30 Poly[(μ(3)-nicotinato-κ(3) O:O′:N)(μ(2)-nicotinato-κ(3) O,O′:N)iron(II)] Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O′-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octahedral coordination geometry but one of the Fe—O bonds is somewhat long [2.522 (2) Å]. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961197/ /pubmed/21202251 http://dx.doi.org/10.1107/S1600536808011045 Text en © Seik Weng Ng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Seik Weng Poly[(μ(3)-nicotinato-κ(3) O:O′:N)(μ(2)-nicotinato-κ(3) O,O′:N)iron(II)] |
| title | Poly[(μ(3)-nicotinato-κ(3)
O:O′:N)(μ(2)-nicotinato-κ(3)
O,O′:N)iron(II)] |
| title_full | Poly[(μ(3)-nicotinato-κ(3)
O:O′:N)(μ(2)-nicotinato-κ(3)
O,O′:N)iron(II)] |
| title_fullStr | Poly[(μ(3)-nicotinato-κ(3)
O:O′:N)(μ(2)-nicotinato-κ(3)
O,O′:N)iron(II)] |
| title_full_unstemmed | Poly[(μ(3)-nicotinato-κ(3)
O:O′:N)(μ(2)-nicotinato-κ(3)
O,O′:N)iron(II)] |
| title_short | Poly[(μ(3)-nicotinato-κ(3)
O:O′:N)(μ(2)-nicotinato-κ(3)
O,O′:N)iron(II)] |
| title_sort | poly[(μ(3)-nicotinato-κ(3)
o:o′:n)(μ(2)-nicotinato-κ(3)
o,o′:n)iron(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961197/ https://www.ncbi.nlm.nih.gov/pubmed/21202251 http://dx.doi.org/10.1107/S1600536808011045 |
| work_keys_str_mv | AT ngseikweng polym3nicotinatok3oonm2nicotinatok3oonironii |