Cargando…
Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrat...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961201/ https://www.ncbi.nlm.nih.gov/pubmed/21202210 http://dx.doi.org/10.1107/S1600536808009860 |
Sumario: | In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are connected by C—H⋯O interactions, while two weak intramolecular C—H⋯O interactions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction. |
---|