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Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate

In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxy­ethyl)-2-methyl-5-nitro­imidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrat...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Balasubramanian, T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961201/
https://www.ncbi.nlm.nih.gov/pubmed/21202210
http://dx.doi.org/10.1107/S1600536808009860
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Balasubramanian, T.
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Balasubramanian, T.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxy­ethyl)-2-methyl-5-nitro­imidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are ­connected by C—H⋯O inter­actions, while two weak intra­molecular C—H⋯O inter­actions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction.
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spelling pubmed-29612012010-12-30 Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate Fun, Hoong-Kun Jebas, Samuel Robinson Balasubramanian, T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxy­ethyl)-2-methyl-5-nitro­imidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are ­connected by C—H⋯O inter­actions, while two weak intra­molecular C—H⋯O inter­actions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961201/ /pubmed/21202210 http://dx.doi.org/10.1107/S1600536808009860 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Balasubramanian, T.
Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title_full Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title_fullStr Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title_full_unstemmed Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title_short Bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
title_sort bis[1-(2-hydroxy­ethyl)-2-methyl-5-nitro-1h-imidazole-κn (3)]silver(i) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961201/
https://www.ncbi.nlm.nih.gov/pubmed/21202210
http://dx.doi.org/10.1107/S1600536808009860
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