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Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate
In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrat...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961201/ https://www.ncbi.nlm.nih.gov/pubmed/21202210 http://dx.doi.org/10.1107/S1600536808009860 |
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author | Fun, Hoong-Kun Jebas, Samuel Robinson Balasubramanian, T. |
author_facet | Fun, Hoong-Kun Jebas, Samuel Robinson Balasubramanian, T. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are connected by C—H⋯O interactions, while two weak intramolecular C—H⋯O interactions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction. |
format | Text |
id | pubmed-2961201 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612012010-12-30 Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate Fun, Hoong-Kun Jebas, Samuel Robinson Balasubramanian, T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are connected by C—H⋯O interactions, while two weak intramolecular C—H⋯O interactions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O—H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961201/ /pubmed/21202210 http://dx.doi.org/10.1107/S1600536808009860 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fun, Hoong-Kun Jebas, Samuel Robinson Balasubramanian, T. Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN (3)]silver(I) nitrate |
title | Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN
(3)]silver(I) nitrate |
title_full | Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN
(3)]silver(I) nitrate |
title_fullStr | Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN
(3)]silver(I) nitrate |
title_full_unstemmed | Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN
(3)]silver(I) nitrate |
title_short | Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN
(3)]silver(I) nitrate |
title_sort | bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1h-imidazole-κn
(3)]silver(i) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961201/ https://www.ncbi.nlm.nih.gov/pubmed/21202210 http://dx.doi.org/10.1107/S1600536808009860 |
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