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Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)

In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra­hedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal–bipyramidal coordination geometry formed by two O [Sn—O...

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Detalles Bibliográficos
Autores principales: Teo, Yin Yin, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961205/
https://www.ncbi.nlm.nih.gov/pubmed/21202235
http://dx.doi.org/10.1107/S1600536808010763
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author Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
author_facet Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
author_sort Teo, Yin Yin
collection PubMed
description In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra­hedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal–bipyramidal coordination geometry formed by two O [Sn—O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn—C = 2.115 (4)–2.128 (4) Å;(Σ C—Sn—C)= 360.0 (6)°].
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spelling pubmed-29612052010-12-30 Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV) Teo, Yin Yin Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra­hedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal–bipyramidal coordination geometry formed by two O [Sn—O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn—C = 2.115 (4)–2.128 (4) Å;(Σ C—Sn—C)= 360.0 (6)°]. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961205/ /pubmed/21202235 http://dx.doi.org/10.1107/S1600536808010763 Text en © Teo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title_full Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title_fullStr Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title_full_unstemmed Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title_short Bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) P:P′]silver(I) bis­(chloro­difluoro­acetato-κO)triphenyl­stannate(IV)
title_sort bis[1,3-bis­(diphenyl­phosphino)propane-κ(2) p:p′]silver(i) bis­(chloro­difluoro­acetato-κo)triphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961205/
https://www.ncbi.nlm.nih.gov/pubmed/21202235
http://dx.doi.org/10.1107/S1600536808010763
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