Chlorido{5,5′-dimeth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III)

In the title complex, [Mn(C(22)H(18)N(2)O(4))Cl], the Mn(III) centre is in a distorted square-pyramidal configuration, with the basal plane formed by the N(2)O(2) donors of the tetra­dentate Schiff base dianion; the two phenolate O atoms and the two imine N atoms are each mutually cis. The chloride ion occupies the apical position. The dihedral angle between the two outer phenolate rings of the tetra­dentate Schiff base ligand is 16.44 (9)°. The central benzene ring makes dihedral angles of 10.64 (9) and 25.17 (10)° with the two outer phenolate rings. In the crystal structure, weak C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules into wave-like face-to-face double layers along the c direction. A π–π inter­action involving the two outer phenolate rings is observed, the centroid–centroid distance being 3.743 (11) Å.