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1-Methyl-3-phenyl­sulfonyl-2-piperidone

The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl­sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol­ecules are connected into centrosymmetric dimers via C...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Olivato, Paulo R., Cerqueira Jr, Carlos R., Vinhato, Elisângela, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961210/
https://www.ncbi.nlm.nih.gov/pubmed/21202324
http://dx.doi.org/10.1107/S1600536808009288
Descripción
Sumario:The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl­sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol­ecules are connected into centrosymmetric dimers via C—H⋯O inter­actions and these associate into layers via C—H⋯O—S contacts. Further C—H⋯O inter­actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing connections between the layers.