1-Methyl-3-phenyl­sulfonyl-2-piperidone

The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl­sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol­ecules are connected into centrosymmetric dimers via C...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Olivato, Paulo R., Cerqueira Jr, Carlos R., Vinhato, Elisângela, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961210/
https://www.ncbi.nlm.nih.gov/pubmed/21202324
http://dx.doi.org/10.1107/S1600536808009288
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author Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Vinhato, Elisângela
Tiekink, Edward R. T.
author_facet Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Vinhato, Elisângela
Tiekink, Edward R. T.
author_sort Zukerman-Schpector, Julio
collection PubMed
description The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl­sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol­ecules are connected into centrosymmetric dimers via C—H⋯O inter­actions and these associate into layers via C—H⋯O—S contacts. Further C—H⋯O inter­actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing connections between the layers.
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spelling pubmed-29612102010-12-30 1-Methyl-3-phenyl­sulfonyl-2-piperidone Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Vinhato, Elisângela Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl­sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol­ecules are connected into centrosymmetric dimers via C—H⋯O inter­actions and these associate into layers via C—H⋯O—S contacts. Further C—H⋯O inter­actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing connections between the layers. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961210/ /pubmed/21202324 http://dx.doi.org/10.1107/S1600536808009288 Text en © Zukerman-Schpector et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Vinhato, Elisângela
Tiekink, Edward R. T.
1-Methyl-3-phenyl­sulfonyl-2-piperidone
title 1-Methyl-3-phenyl­sulfonyl-2-piperidone
title_full 1-Methyl-3-phenyl­sulfonyl-2-piperidone
title_fullStr 1-Methyl-3-phenyl­sulfonyl-2-piperidone
title_full_unstemmed 1-Methyl-3-phenyl­sulfonyl-2-piperidone
title_short 1-Methyl-3-phenyl­sulfonyl-2-piperidone
title_sort 1-methyl-3-phenyl­sulfonyl-2-piperidone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961210/
https://www.ncbi.nlm.nih.gov/pubmed/21202324
http://dx.doi.org/10.1107/S1600536808009288
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AT cerqueirajrcarlosr 1methyl3phenylsulfonyl2piperidone
AT vinhatoelisangela 1methyl3phenylsulfonyl2piperidone
AT tiekinkedwardrt 1methyl3phenylsulfonyl2piperidone

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