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Tetraaquabis(biuret-κ(2) O,O′)gadolinium(III) trichloride
In the title compound, [Gd(C(2)H(5)N(3)O(2))(2)(H(2)O)(4)]Cl(3), which is isostrucutural with its yttrium analogue, the Gd(3+) ion (site symmetry 2) is bonded to eight O atoms (arising from two O,O′-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangeme...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961212/ https://www.ncbi.nlm.nih.gov/pubmed/21202175 http://dx.doi.org/10.1107/S1600536808008660 |
| _version_ | 1782188928470614016 |
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| author | Harrison, William T. A. |
| author_facet | Harrison, William T. A. |
| author_sort | Harrison, William T. A. |
| collection | PubMed |
| description | In the title compound, [Gd(C(2)H(5)N(3)O(2))(2)(H(2)O)(4)]Cl(3), which is isostrucutural with its yttrium analogue, the Gd(3+) ion (site symmetry 2) is bonded to eight O atoms (arising from two O,O′-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2. |
| format | Text |
| id | pubmed-2961212 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29612122010-12-30 Tetraaquabis(biuret-κ(2) O,O′)gadolinium(III) trichloride Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Gd(C(2)H(5)N(3)O(2))(2)(H(2)O)(4)]Cl(3), which is isostrucutural with its yttrium analogue, the Gd(3+) ion (site symmetry 2) is bonded to eight O atoms (arising from two O,O′-bidentate biuret molecules and four water molecules) in a distorted square-antiprismatic arrangement. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961212/ /pubmed/21202175 http://dx.doi.org/10.1107/S1600536808008660 Text en © William T. A. Harrison 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Harrison, William T. A. Tetraaquabis(biuret-κ(2) O,O′)gadolinium(III) trichloride |
| title | Tetraaquabis(biuret-κ(2)
O,O′)gadolinium(III) trichloride |
| title_full | Tetraaquabis(biuret-κ(2)
O,O′)gadolinium(III) trichloride |
| title_fullStr | Tetraaquabis(biuret-κ(2)
O,O′)gadolinium(III) trichloride |
| title_full_unstemmed | Tetraaquabis(biuret-κ(2)
O,O′)gadolinium(III) trichloride |
| title_short | Tetraaquabis(biuret-κ(2)
O,O′)gadolinium(III) trichloride |
| title_sort | tetraaquabis(biuret-κ(2)
o,o′)gadolinium(iii) trichloride |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961212/ https://www.ncbi.nlm.nih.gov/pubmed/21202175 http://dx.doi.org/10.1107/S1600536808008660 |
| work_keys_str_mv | AT harrisonwilliamta tetraaquabisbiuretk2oogadoliniumiiitrichloride |