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Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]

In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichloro­phen­oxy)acetate ligands and two water mol­ecules, and displays a distorted square-anti­prismatic coordination geometry. The compo...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Huang, Xiang-Hu, Yan, Jian-Bin, Ma, De-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961213/
https://www.ncbi.nlm.nih.gov/pubmed/21202200
http://dx.doi.org/10.1107/S1600536808009379
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author Song, Wen-Dong
Huang, Xiang-Hu
Yan, Jian-Bin
Ma, De-Yun
author_facet Song, Wen-Dong
Huang, Xiang-Hu
Yan, Jian-Bin
Ma, De-Yun
author_sort Song, Wen-Dong
collection PubMed
description In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichloro­phen­oxy)acetate ligands and two water mol­ecules, and displays a distorted square-anti­prismatic coordination geometry. The compound forms an infinite zigzag chain through connection of the metal centers by (2,4-dichlorphen­oxy)acetate ligands and hydrogen bonding of coordinated and inter­stitial water mol­ecules. These chains are further hydrogen bonded with neighboring chains, forming a supra­molecular network.
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spelling pubmed-29612132010-12-30 Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate] Song, Wen-Dong Huang, Xiang-Hu Yan, Jian-Bin Ma, De-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichloro­phen­oxy)acetate ligands and two water mol­ecules, and displays a distorted square-anti­prismatic coordination geometry. The compound forms an infinite zigzag chain through connection of the metal centers by (2,4-dichlorphen­oxy)acetate ligands and hydrogen bonding of coordinated and inter­stitial water mol­ecules. These chains are further hydrogen bonded with neighboring chains, forming a supra­molecular network. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961213/ /pubmed/21202200 http://dx.doi.org/10.1107/S1600536808009379 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Huang, Xiang-Hu
Yan, Jian-Bin
Ma, De-Yun
Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title_full Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title_fullStr Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title_full_unstemmed Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title_short Poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(II)] monohydrate]
title_sort poly[[diaqua­bis[μ-(2,4-dichloro­phen­oxy)acetato]calcium(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961213/
https://www.ncbi.nlm.nih.gov/pubmed/21202200
http://dx.doi.org/10.1107/S1600536808009379
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