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Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate]
In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichlorophenoxy)acetate ligands and two water molecules, and displays a distorted square-antiprismatic coordination geometry. The compo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961213/ https://www.ncbi.nlm.nih.gov/pubmed/21202200 http://dx.doi.org/10.1107/S1600536808009379 |
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author | Song, Wen-Dong Huang, Xiang-Hu Yan, Jian-Bin Ma, De-Yun |
author_facet | Song, Wen-Dong Huang, Xiang-Hu Yan, Jian-Bin Ma, De-Yun |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichlorophenoxy)acetate ligands and two water molecules, and displays a distorted square-antiprismatic coordination geometry. The compound forms an infinite zigzag chain through connection of the metal centers by (2,4-dichlorphenoxy)acetate ligands and hydrogen bonding of coordinated and interstitial water molecules. These chains are further hydrogen bonded with neighboring chains, forming a supramolecular network. |
format | Text |
id | pubmed-2961213 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612132010-12-30 Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] Song, Wen-Dong Huang, Xiang-Hu Yan, Jian-Bin Ma, De-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichlorophenoxy)acetate ligands and two water molecules, and displays a distorted square-antiprismatic coordination geometry. The compound forms an infinite zigzag chain through connection of the metal centers by (2,4-dichlorphenoxy)acetate ligands and hydrogen bonding of coordinated and interstitial water molecules. These chains are further hydrogen bonded with neighboring chains, forming a supramolecular network. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961213/ /pubmed/21202200 http://dx.doi.org/10.1107/S1600536808009379 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Huang, Xiang-Hu Yan, Jian-Bin Ma, De-Yun Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title | Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title_full | Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title_fullStr | Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title_full_unstemmed | Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title_short | Poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(II)] monohydrate] |
title_sort | poly[[diaquabis[μ-(2,4-dichlorophenoxy)acetato]calcium(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961213/ https://www.ncbi.nlm.nih.gov/pubmed/21202200 http://dx.doi.org/10.1107/S1600536808009379 |
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