Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))

The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C—H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro­methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, wit...

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Detalles Bibliográficos
Autores principales: Zhou, Jin, Wang, Qibao, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961217/
https://www.ncbi.nlm.nih.gov/pubmed/21202224
http://dx.doi.org/10.1107/S1600536808010301
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author Zhou, Jin
Wang, Qibao
Sun, Hongjian
author_facet Zhou, Jin
Wang, Qibao
Sun, Hongjian
author_sort Zhou, Jin
collection PubMed
description The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C—H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro­methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.
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spelling pubmed-29612172010-12-30 Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II)) Zhou, Jin Wang, Qibao Sun, Hongjian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C—H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro­methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961217/ /pubmed/21202224 http://dx.doi.org/10.1107/S1600536808010301 Text en © Zhou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Jin
Wang, Qibao
Sun, Hongjian
Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title_full Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title_fullStr Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title_full_unstemmed Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title_short Di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(II))
title_sort di-μ-chlorido-bis­({9-[(2,6-diisopropyl­phen­yl)imino­meth­yl]anthracen-1-yl}palladium(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961217/
https://www.ncbi.nlm.nih.gov/pubmed/21202224
http://dx.doi.org/10.1107/S1600536808010301
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AT wangqibao dimchloridobis926diisopropylphenyliminomethylanthracen1ylpalladiumii
AT sunhongjian dimchloridobis926diisopropylphenyliminomethylanthracen1ylpalladiumii

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