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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato)-κO;κ(2) O,O′-cobalt(II)
In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxybenzoate anions in a distorted trigonal bipyramidal geometry. The carboxylate group of one o...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961220/ https://www.ncbi.nlm.nih.gov/pubmed/21202260 http://dx.doi.org/10.1107/S1600536808012002 |
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author | Zhao, Pei-Zheng Xuan, Xiao-Peng Tang, Qing-Hu |
author_facet | Zhao, Pei-Zheng Xuan, Xiao-Peng Tang, Qing-Hu |
author_sort | Zhao, Pei-Zheng |
collection | PubMed |
description | In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxybenzoate anions in a distorted trigonal bipyramidal geometry. The carboxylate group of one of the two 2-hydroxybenzoate anions is monodentate with a normal Co—O distance [1.9804 (18) Å], while the other is bidentate with two longer Co—O bonds [2.1981 (18) and 2.1359 (19) Å]. The crystal structure is stabilized by aromatic π–π stacking interactions [centroid–centroid distances of 4.0380 (3) and 3.8216 (3) Å between dmphen/dmphen and benzene/dmphen rings, respectively] and C—H⋯π(benzene) interactions. |
format | Text |
id | pubmed-2961220 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612202010-12-30 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato)-κO;κ(2) O,O′-cobalt(II) Zhao, Pei-Zheng Xuan, Xiao-Peng Tang, Qing-Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxybenzoate anions in a distorted trigonal bipyramidal geometry. The carboxylate group of one of the two 2-hydroxybenzoate anions is monodentate with a normal Co—O distance [1.9804 (18) Å], while the other is bidentate with two longer Co—O bonds [2.1981 (18) and 2.1359 (19) Å]. The crystal structure is stabilized by aromatic π–π stacking interactions [centroid–centroid distances of 4.0380 (3) and 3.8216 (3) Å between dmphen/dmphen and benzene/dmphen rings, respectively] and C—H⋯π(benzene) interactions. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961220/ /pubmed/21202260 http://dx.doi.org/10.1107/S1600536808012002 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Zhao, Pei-Zheng Xuan, Xiao-Peng Tang, Qing-Hu (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato)-κO;κ(2) O,O′-cobalt(II) |
title | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato)-κO;κ(2)
O,O′-cobalt(II) |
title_full | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato)-κO;κ(2)
O,O′-cobalt(II) |
title_fullStr | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato)-κO;κ(2)
O,O′-cobalt(II) |
title_full_unstemmed | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato)-κO;κ(2)
O,O′-cobalt(II) |
title_short | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato)-κO;κ(2)
O,O′-cobalt(II) |
title_sort | (2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)bis(2-hydroxybenzoato)-κo;κ(2)
o,o′-cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961220/ https://www.ncbi.nlm.nih.gov/pubmed/21202260 http://dx.doi.org/10.1107/S1600536808012002 |
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