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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)

In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxy­benzoate anions in a distorted trigonal bipyramidal geometry. The carboxyl­ate group of one o...

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Detalles Bibliográficos
Autores principales: Zhao, Pei-Zheng, Xuan, Xiao-Peng, Tang, Qing-Hu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961220/
https://www.ncbi.nlm.nih.gov/pubmed/21202260
http://dx.doi.org/10.1107/S1600536808012002
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author Zhao, Pei-Zheng
Xuan, Xiao-Peng
Tang, Qing-Hu
author_facet Zhao, Pei-Zheng
Xuan, Xiao-Peng
Tang, Qing-Hu
author_sort Zhao, Pei-Zheng
collection PubMed
description In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxy­benzoate anions in a distorted trigonal bipyramidal geometry. The carboxyl­ate group of one of the two 2-hydroxy­benzoate anions is monodentate with a normal Co—O distance [1.9804 (18) Å], while the other is bidentate with two longer Co—O bonds [2.1981 (18) and 2.1359 (19) Å]. The crystal structure is stabilized by aromatic π–π stacking inter­actions [centroid–centroid distances of 4.0380 (3) and 3.8216 (3) Å between dmphen/dmphen and benzene/dmphen rings, respectively] and C—H⋯π(benzene) inter­actions.
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spelling pubmed-29612202010-12-30 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II) Zhao, Pei-Zheng Xuan, Xiao-Peng Tang, Qing-Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(3))(2)(C(14)H(12)N(2))], the Co(II) ion is five-coordinated by two N atoms from one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and three O atoms from two 2-hydroxy­benzoate anions in a distorted trigonal bipyramidal geometry. The carboxyl­ate group of one of the two 2-hydroxy­benzoate anions is monodentate with a normal Co—O distance [1.9804 (18) Å], while the other is bidentate with two longer Co—O bonds [2.1981 (18) and 2.1359 (19) Å]. The crystal structure is stabilized by aromatic π–π stacking inter­actions [centroid–centroid distances of 4.0380 (3) and 3.8216 (3) Å between dmphen/dmphen and benzene/dmphen rings, respectively] and C—H⋯π(benzene) inter­actions. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961220/ /pubmed/21202260 http://dx.doi.org/10.1107/S1600536808012002 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhao, Pei-Zheng
Xuan, Xiao-Peng
Tang, Qing-Hu
(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title_full (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title_fullStr (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title_full_unstemmed (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title_short (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO;κ(2) O,O′-cobalt(II)
title_sort (2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)bis­(2-hydroxy­benzoato)-κo;κ(2) o,o′-cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961220/
https://www.ncbi.nlm.nih.gov/pubmed/21202260
http://dx.doi.org/10.1107/S1600536808012002
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