Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate

In the title compound, [Cu(ClO(4))(2)(C(16)H(16)N(4)O)(2)]·2CH(3)CN, the Cu(II) atom, located on an inversion center, is in a tetra­gonally distorted octa­hedral environment, coordinated by four N atoms of two bidentate 3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole ligands in equato...

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Detalles Bibliográficos
Autores principales: Huang, Liaocheng, Wang, Zuoxiang, Zhang, Xiaoming, Wu, Pingfeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961222/
https://www.ncbi.nlm.nih.gov/pubmed/21202261
http://dx.doi.org/10.1107/S1600536808012026
Descripción
Sumario:In the title compound, [Cu(ClO(4))(2)(C(16)H(16)N(4)O)(2)]·2CH(3)CN, the Cu(II) atom, located on an inversion center, is in a tetra­gonally distorted octa­hedral environment, coordinated by four N atoms of two bidentate 3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole ligands in equatorial positions and by the O atoms of two perchlorate groups in axial positions. The long axial Cu—O bond of 2.4743 (17) Å is the result of the Jahn–Teller effect.

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