Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate

In the title compound, [Cu(ClO(4))(2)(C(16)H(16)N(4)O)(2)]·2CH(3)CN, the Cu(II) atom, located on an inversion center, is in a tetra­gonally distorted octa­hedral environment, coordinated by four N atoms of two bidentate 3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole ligands in equato...

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Detalles Bibliográficos
Autores principales: Huang, Liaocheng, Wang, Zuoxiang, Zhang, Xiaoming, Wu, Pingfeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961222/
https://www.ncbi.nlm.nih.gov/pubmed/21202261
http://dx.doi.org/10.1107/S1600536808012026
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author Huang, Liaocheng
Wang, Zuoxiang
Zhang, Xiaoming
Wu, Pingfeng
author_facet Huang, Liaocheng
Wang, Zuoxiang
Zhang, Xiaoming
Wu, Pingfeng
author_sort Huang, Liaocheng
collection PubMed
description In the title compound, [Cu(ClO(4))(2)(C(16)H(16)N(4)O)(2)]·2CH(3)CN, the Cu(II) atom, located on an inversion center, is in a tetra­gonally distorted octa­hedral environment, coordinated by four N atoms of two bidentate 3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole ligands in equatorial positions and by the O atoms of two perchlorate groups in axial positions. The long axial Cu—O bond of 2.4743 (17) Å is the result of the Jahn–Teller effect.
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spelling pubmed-29612222010-12-30 Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate Huang, Liaocheng Wang, Zuoxiang Zhang, Xiaoming Wu, Pingfeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(16)H(16)N(4)O)(2)]·2CH(3)CN, the Cu(II) atom, located on an inversion center, is in a tetra­gonally distorted octa­hedral environment, coordinated by four N atoms of two bidentate 3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole ligands in equatorial positions and by the O atoms of two perchlorate groups in axial positions. The long axial Cu—O bond of 2.4743 (17) Å is the result of the Jahn–Teller effect. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961222/ /pubmed/21202261 http://dx.doi.org/10.1107/S1600536808012026 Text en © Huang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Liaocheng
Wang, Zuoxiang
Zhang, Xiaoming
Wu, Pingfeng
Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title_full Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title_fullStr Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title_full_unstemmed Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title_short Bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]bis­(perchlorato-κO)copper(II) acetonitrile disolvate
title_sort bis[3-ethyl-4-(4-methoxy­phen­yl)-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]bis­(perchlorato-κo)copper(ii) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961222/
https://www.ncbi.nlm.nih.gov/pubmed/21202261
http://dx.doi.org/10.1107/S1600536808012026
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AT wangzuoxiang bis3ethyl44methoxyphenyl52pyridyl4h124triazolek2n1n5bisperchloratokocopperiiacetonitriledisolvate
AT zhangxiaoming bis3ethyl44methoxyphenyl52pyridyl4h124triazolek2n1n5bisperchloratokocopperiiacetonitriledisolvate
AT wupingfeng bis3ethyl44methoxyphenyl52pyridyl4h124triazolek2n1n5bisperchloratokocopperiiacetonitriledisolvate

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