(μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]

The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol­ecules, each molecule lying on a centre of symmetry. The thiol­ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa­hedral geometry. In the octa­hedral environm...

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Detalles Bibliográficos
Autores principales: Wong, Richard Chee Seng, Ooi, Mei Lee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961228/
https://www.ncbi.nlm.nih.gov/pubmed/21202229
http://dx.doi.org/10.1107/S1600536808010751
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author Wong, Richard Chee Seng
Ooi, Mei Lee
Ng, Seik Weng
author_facet Wong, Richard Chee Seng
Ooi, Mei Lee
Ng, Seik Weng
author_sort Wong, Richard Chee Seng
collection PubMed
description The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol­ecules, each molecule lying on a centre of symmetry. The thiol­ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa­hedral geometry. In the octa­hedral environment the two ligating S atoms are in a cis arrangement.
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spelling pubmed-29612282010-12-30 (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)] Wong, Richard Chee Seng Ooi, Mei Lee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol­ecules, each molecule lying on a centre of symmetry. The thiol­ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa­hedral geometry. In the octa­hedral environment the two ligating S atoms are in a cis arrangement. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961228/ /pubmed/21202229 http://dx.doi.org/10.1107/S1600536808010751 Text en © Wong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wong, Richard Chee Seng
Ooi, Mei Lee
Ng, Seik Weng
(μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title_full (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title_fullStr (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title_full_unstemmed (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title_short (μ-4-Methyl­benzene­thiol­ato-κ(2) S:S)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(II)]
title_sort (μ-4-methyl­benzene­thiol­ato-κ(2) s:s)bis­[carbon­yl(η(5)-cyclo­penta­dien­yl)molybdenum(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961228/
https://www.ncbi.nlm.nih.gov/pubmed/21202229
http://dx.doi.org/10.1107/S1600536808010751
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AT ooimeilee m4methylbenzenethiolatok2ssbiscarbonylē5cyclopentadienylmolybdenumii
AT ngseikweng m4methylbenzenethiolatok2ssbiscarbonylē5cyclopentadienylmolybdenumii

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