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2,2′-(Iminodimethylene)dibenzimidazolium bis(perchlorate) methanol solvate
In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (−)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent molecules are linked to the cation by N—H⋯O hydrogen bonds. In the crystal structure, the combination of N—H⋯O and O—H⋯O hydrogen bond...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961233/ https://www.ncbi.nlm.nih.gov/pubmed/21202284 http://dx.doi.org/10.1107/S1600536808008519 |
| Sumario: | In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (−)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent molecules are linked to the cation by N—H⋯O hydrogen bonds. In the crystal structure, the combination of N—H⋯O and O—H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π–π interactions, forming a three-dimensional network. |
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