2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate

In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (−)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol­ecules are linked to the cation by N—H⋯O hydrogen bonds. In the crystal structure, the combination of N—H⋯O and O—H⋯O hydrogen bond...

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Detalles Bibliográficos
Autores principales: Zhou, Chun-Shan, Huang, Xue-Ying, Meng, Xiang-Gao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961233/
https://www.ncbi.nlm.nih.gov/pubmed/21202284
http://dx.doi.org/10.1107/S1600536808008519
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author Zhou, Chun-Shan
Huang, Xue-Ying
Meng, Xiang-Gao
author_facet Zhou, Chun-Shan
Huang, Xue-Ying
Meng, Xiang-Gao
author_sort Zhou, Chun-Shan
collection PubMed
description In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (−)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol­ecules are linked to the cation by N—H⋯O hydrogen bonds. In the crystal structure, the combination of N—H⋯O and O—H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π–π inter­actions, forming a three-dimensional network.
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spelling pubmed-29612332010-12-30 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate Zhou, Chun-Shan Huang, Xue-Ying Meng, Xiang-Gao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (−)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol­ecules are linked to the cation by N—H⋯O hydrogen bonds. In the crystal structure, the combination of N—H⋯O and O—H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π–π inter­actions, forming a three-dimensional network. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961233/ /pubmed/21202284 http://dx.doi.org/10.1107/S1600536808008519 Text en © Zhou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Chun-Shan
Huang, Xue-Ying
Meng, Xiang-Gao
2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title_full 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title_fullStr 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title_full_unstemmed 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title_short 2,2′-(Imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
title_sort 2,2′-(imino­dimethyl­ene)dibenz­imid­azol­ium bis­(perchlorate) methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961233/
https://www.ncbi.nlm.nih.gov/pubmed/21202284
http://dx.doi.org/10.1107/S1600536808008519
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AT huangxueying 22iminodimethylenedibenzimidazoliumbisperchloratemethanolsolvate
AT mengxianggao 22iminodimethylenedibenzimidazoliumbisperchloratemethanolsolvate

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