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3-Chloro-N-(3-chloro­phen­yl)benzamide

In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent mol­ecules. In one mol­ecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other mol­ecule. This relationship is also observed...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961234/
https://www.ncbi.nlm.nih.gov/pubmed/21202429
http://dx.doi.org/10.1107/S1600536808012099
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author Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent mol­ecules. In one mol­ecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other mol­ecule. This relationship is also observed between the C=O bond and the meta-chloro substituent of its attached ring. The amide –NHCO– group makes dihedral angles of 31.5 (4) and 34.7 (3)° with the aniline rings; it makes dihedral angles of 37.4 (3) and 37.2 (3)° with the benzoyl rings. The two rings are nearly coplanar, with dihedral angles of 9.1 (2) and 7.3 (3)° in the two independent mol­ecules. Adjacent mol­ecules are linked into infinite chains through N—H⋯O hydrogen bonds.
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spelling pubmed-29612342010-12-30 3-Chloro-N-(3-chloro­phen­yl)benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent mol­ecules. In one mol­ecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other mol­ecule. This relationship is also observed between the C=O bond and the meta-chloro substituent of its attached ring. The amide –NHCO– group makes dihedral angles of 31.5 (4) and 34.7 (3)° with the aniline rings; it makes dihedral angles of 37.4 (3) and 37.2 (3)° with the benzoyl rings. The two rings are nearly coplanar, with dihedral angles of 9.1 (2) and 7.3 (3)° in the two independent mol­ecules. Adjacent mol­ecules are linked into infinite chains through N—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961234/ /pubmed/21202429 http://dx.doi.org/10.1107/S1600536808012099 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
3-Chloro-N-(3-chloro­phen­yl)benzamide
title 3-Chloro-N-(3-chloro­phen­yl)benzamide
title_full 3-Chloro-N-(3-chloro­phen­yl)benzamide
title_fullStr 3-Chloro-N-(3-chloro­phen­yl)benzamide
title_full_unstemmed 3-Chloro-N-(3-chloro­phen­yl)benzamide
title_short 3-Chloro-N-(3-chloro­phen­yl)benzamide
title_sort 3-chloro-n-(3-chloro­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961234/
https://www.ncbi.nlm.nih.gov/pubmed/21202429
http://dx.doi.org/10.1107/S1600536808012099
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