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3-Chloro-N-(3-chlorophenyl)benzamide
In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent molecules. In one molecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other molecule. This relationship is also observed...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961234/ https://www.ncbi.nlm.nih.gov/pubmed/21202429 http://dx.doi.org/10.1107/S1600536808012099 |
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author | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent molecules. In one molecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other molecule. This relationship is also observed between the C=O bond and the meta-chloro substituent of its attached ring. The amide –NHCO– group makes dihedral angles of 31.5 (4) and 34.7 (3)° with the aniline rings; it makes dihedral angles of 37.4 (3) and 37.2 (3)° with the benzoyl rings. The two rings are nearly coplanar, with dihedral angles of 9.1 (2) and 7.3 (3)° in the two independent molecules. Adjacent molecules are linked into infinite chains through N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961234 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612342010-12-30 3-Chloro-N-(3-chlorophenyl)benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N—H and C=O bonds are anti to each other in the two independent molecules. In one molecule, the N—H bond is syn to the meta-chloro group of the attached ring; it is anti in the other molecule. This relationship is also observed between the C=O bond and the meta-chloro substituent of its attached ring. The amide –NHCO– group makes dihedral angles of 31.5 (4) and 34.7 (3)° with the aniline rings; it makes dihedral angles of 37.4 (3) and 37.2 (3)° with the benzoyl rings. The two rings are nearly coplanar, with dihedral angles of 9.1 (2) and 7.3 (3)° in the two independent molecules. Adjacent molecules are linked into infinite chains through N—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961234/ /pubmed/21202429 http://dx.doi.org/10.1107/S1600536808012099 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut 3-Chloro-N-(3-chlorophenyl)benzamide |
title | 3-Chloro-N-(3-chlorophenyl)benzamide |
title_full | 3-Chloro-N-(3-chlorophenyl)benzamide |
title_fullStr | 3-Chloro-N-(3-chlorophenyl)benzamide |
title_full_unstemmed | 3-Chloro-N-(3-chlorophenyl)benzamide |
title_short | 3-Chloro-N-(3-chlorophenyl)benzamide |
title_sort | 3-chloro-n-(3-chlorophenyl)benzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961234/ https://www.ncbi.nlm.nih.gov/pubmed/21202429 http://dx.doi.org/10.1107/S1600536808012099 |
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