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(2,2′-Bipyridyl-κ(2) N,N′)tetrakis(4-methylbenzoato-κO)manganese(II)
In the title mononuclear complex, [Mn(C(8)H(7)O(2))(4)(C(10)H(8)N(2))], the Mn(II) atom lies on a twofold rotation axis and has a distorted octahedral coordination geometry defined by four O atoms from four 4-methylbenzoate ligands and two N atoms from one 2,2′-bipyridyl ligand. The crystal struct...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961244/ https://www.ncbi.nlm.nih.gov/pubmed/21202215 http://dx.doi.org/10.1107/S160053680800994X |
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author | Song, Wen-Dong Wang, Hao Ma, De-Yun |
author_facet | Song, Wen-Dong Wang, Hao Ma, De-Yun |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the title mononuclear complex, [Mn(C(8)H(7)O(2))(4)(C(10)H(8)N(2))], the Mn(II) atom lies on a twofold rotation axis and has a distorted octahedral coordination geometry defined by four O atoms from four 4-methylbenzoate ligands and two N atoms from one 2,2′-bipyridyl ligand. The crystal structure is stabilized by intermolecular hydrogen bonds and π–π stacking interactions [the centroid–centroid distance between the parallel pyridyl ring of a 2,2′-bipyridyl and benzene ring of a 4-methylbenzoic group of a neighboring complex is 3.839 (2) Å]. |
format | Text |
id | pubmed-2961244 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612442010-12-30 (2,2′-Bipyridyl-κ(2) N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) Song, Wen-Dong Wang, Hao Ma, De-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Mn(C(8)H(7)O(2))(4)(C(10)H(8)N(2))], the Mn(II) atom lies on a twofold rotation axis and has a distorted octahedral coordination geometry defined by four O atoms from four 4-methylbenzoate ligands and two N atoms from one 2,2′-bipyridyl ligand. The crystal structure is stabilized by intermolecular hydrogen bonds and π–π stacking interactions [the centroid–centroid distance between the parallel pyridyl ring of a 2,2′-bipyridyl and benzene ring of a 4-methylbenzoic group of a neighboring complex is 3.839 (2) Å]. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961244/ /pubmed/21202215 http://dx.doi.org/10.1107/S160053680800994X Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Wang, Hao Ma, De-Yun (2,2′-Bipyridyl-κ(2) N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title | (2,2′-Bipyridyl-κ(2)
N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title_full | (2,2′-Bipyridyl-κ(2)
N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title_fullStr | (2,2′-Bipyridyl-κ(2)
N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title_full_unstemmed | (2,2′-Bipyridyl-κ(2)
N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title_short | (2,2′-Bipyridyl-κ(2)
N,N′)tetrakis(4-methylbenzoato-κO)manganese(II) |
title_sort | (2,2′-bipyridyl-κ(2)
n,n′)tetrakis(4-methylbenzoato-κo)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961244/ https://www.ncbi.nlm.nih.gov/pubmed/21202215 http://dx.doi.org/10.1107/S160053680800994X |
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