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Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II)
In the molecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octahedral geometry. The face-to-face separation of 3.561 (5) Å...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961246/ https://www.ncbi.nlm.nih.gov/pubmed/21202217 http://dx.doi.org/10.1107/S1600536808010076 |
| _version_ | 1782188936619098112 |
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| author | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_facet | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_sort | Zhang, Bing-Yu |
| collection | PubMed |
| description | In the molecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octahedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π–π stacking between the pyridine rings. The structure also contains intermolecular O—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding. |
| format | Text |
| id | pubmed-2961246 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29612462010-12-30 Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octahedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π–π stacking between the pyridine rings. The structure also contains intermolecular O—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961246/ /pubmed/21202217 http://dx.doi.org/10.1107/S1600536808010076 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title | Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title_full | Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title_fullStr | Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title_full_unstemmed | Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title_short | Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II) |
| title_sort | tetraaquabis(pyridine-3-sulfonato-κn)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961246/ https://www.ncbi.nlm.nih.gov/pubmed/21202217 http://dx.doi.org/10.1107/S1600536808010076 |
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