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2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one
In the molecule of the title compound, C(18)H(13)Cl(2)N(3)O(2)S(2), the thiazolidinone ring has an envelope conformation with the S atom displaced by 0.394 (3) Å from the plane of the other ring atoms. The thiadiazole ring is oriented at a dihedral angle of 7.40 (4)° with respect to the 4-methoxy...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961251/ https://www.ncbi.nlm.nih.gov/pubmed/21202287 http://dx.doi.org/10.1107/S1600536808008465 |
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author | Wan, Rong Yin, Li-He Han, Feng Wang, Bin Wang, Jin-Tang |
author_facet | Wan, Rong Yin, Li-He Han, Feng Wang, Bin Wang, Jin-Tang |
author_sort | Wan, Rong |
collection | PubMed |
description | In the molecule of the title compound, C(18)H(13)Cl(2)N(3)O(2)S(2), the thiazolidinone ring has an envelope conformation with the S atom displaced by 0.394 (3) Å from the plane of the other ring atoms. The thiadiazole ring is oriented at a dihedral angle of 7.40 (4)° with respect to the 4-methoxyphenyl ring. Intramolecular C—H⋯S, C—H⋯N and C—H⋯Cl hydrogen bonds result in the formation of two planar and two non-planar five-membered rings. The planar five-membered rings are oriented at a dihedral angle of 6.23 (3)°. The 2,4-dichlorophenyl ring is oriented at dihedral angles of 84.21 (4) and 83.55 (3)° with respect to the thiadiazole and 4-methoxyphenyl rings, respectively. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. |
format | Text |
id | pubmed-2961251 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612512010-12-30 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one Wan, Rong Yin, Li-He Han, Feng Wang, Bin Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(18)H(13)Cl(2)N(3)O(2)S(2), the thiazolidinone ring has an envelope conformation with the S atom displaced by 0.394 (3) Å from the plane of the other ring atoms. The thiadiazole ring is oriented at a dihedral angle of 7.40 (4)° with respect to the 4-methoxyphenyl ring. Intramolecular C—H⋯S, C—H⋯N and C—H⋯Cl hydrogen bonds result in the formation of two planar and two non-planar five-membered rings. The planar five-membered rings are oriented at a dihedral angle of 6.23 (3)°. The 2,4-dichlorophenyl ring is oriented at dihedral angles of 84.21 (4) and 83.55 (3)° with respect to the thiadiazole and 4-methoxyphenyl rings, respectively. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. International Union of Crystallography 2008-04-04 /pmc/articles/PMC2961251/ /pubmed/21202287 http://dx.doi.org/10.1107/S1600536808008465 Text en © Wan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wan, Rong Yin, Li-He Han, Feng Wang, Bin Wang, Jin-Tang 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title | 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title_full | 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title_fullStr | 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title_full_unstemmed | 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title_short | 2-(2,4-Dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
title_sort | 2-(2,4-dichlorophenyl)-3-[5-(4-methoxyphenyl)-1,3,4-thiadiazol-2-yl]-1,3-thiazolidin-4-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961251/ https://www.ncbi.nlm.nih.gov/pubmed/21202287 http://dx.doi.org/10.1107/S1600536808008465 |
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