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(2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title mol­ecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from...

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Detalles Bibliográficos
Autores principales: Dong, Feng-Ying, Sun, Yun-Ming, Li, Yan-Tuan, Wu, Zhi-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961256/
https://www.ncbi.nlm.nih.gov/pubmed/21202216
http://dx.doi.org/10.1107/S1600536808009975
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author Dong, Feng-Ying
Sun, Yun-Ming
Li, Yan-Tuan
Wu, Zhi-Yong
author_facet Dong, Feng-Ying
Sun, Yun-Ming
Li, Yan-Tuan
Wu, Zhi-Yong
author_sort Dong, Feng-Ying
collection PubMed
description In the title mol­ecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from a perchlorate anion in a distorted square-pyramidal geometry. Three O atoms of the perchlorate anion are rotationally disordered between two orientations, with occupancies of 0.525 (13) and 0.475 (13). In the crystal structure, two mol­ecules related by a centre of symmetry are paired in such a way that the phenolate O atom from one mol­ecule completes the distorted octa­hedral Cu coordination in another mol­ecule [Cu⋯O = 2.704 (2) Å].
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spelling pubmed-29612562010-12-30 (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Dong, Feng-Ying Sun, Yun-Ming Li, Yan-Tuan Wu, Zhi-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from a perchlorate anion in a distorted square-pyramidal geometry. Three O atoms of the perchlorate anion are rotationally disordered between two orientations, with occupancies of 0.525 (13) and 0.475 (13). In the crystal structure, two mol­ecules related by a centre of symmetry are paired in such a way that the phenolate O atom from one mol­ecule completes the distorted octa­hedral Cu coordination in another mol­ecule [Cu⋯O = 2.704 (2) Å]. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961256/ /pubmed/21202216 http://dx.doi.org/10.1107/S1600536808009975 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Feng-Ying
Sun, Yun-Ming
Li, Yan-Tuan
Wu, Zhi-Yong
(2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short (2-Formyl-6-methoxy­phenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort (2-formyl-6-methoxy­phenolato-κ(2) o (1),o (2))(perchlorato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961256/
https://www.ncbi.nlm.nih.gov/pubmed/21202216
http://dx.doi.org/10.1107/S1600536808009975
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