Cargando…
(2-Formyl-6-methoxyphenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title molecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961256/ https://www.ncbi.nlm.nih.gov/pubmed/21202216 http://dx.doi.org/10.1107/S1600536808009975 |
_version_ | 1782188938990977024 |
---|---|
author | Dong, Feng-Ying Sun, Yun-Ming Li, Yan-Tuan Wu, Zhi-Yong |
author_facet | Dong, Feng-Ying Sun, Yun-Ming Li, Yan-Tuan Wu, Zhi-Yong |
author_sort | Dong, Feng-Ying |
collection | PubMed |
description | In the title molecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from a perchlorate anion in a distorted square-pyramidal geometry. Three O atoms of the perchlorate anion are rotationally disordered between two orientations, with occupancies of 0.525 (13) and 0.475 (13). In the crystal structure, two molecules related by a centre of symmetry are paired in such a way that the phenolate O atom from one molecule completes the distorted octahedral Cu coordination in another molecule [Cu⋯O = 2.704 (2) Å]. |
format | Text |
id | pubmed-2961256 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612562010-12-30 (2-Formyl-6-methoxyphenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Dong, Feng-Ying Sun, Yun-Ming Li, Yan-Tuan Wu, Zhi-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu—O = 2.510 (3) Å] from a perchlorate anion in a distorted square-pyramidal geometry. Three O atoms of the perchlorate anion are rotationally disordered between two orientations, with occupancies of 0.525 (13) and 0.475 (13). In the crystal structure, two molecules related by a centre of symmetry are paired in such a way that the phenolate O atom from one molecule completes the distorted octahedral Cu coordination in another molecule [Cu⋯O = 2.704 (2) Å]. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961256/ /pubmed/21202216 http://dx.doi.org/10.1107/S1600536808009975 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dong, Feng-Ying Sun, Yun-Ming Li, Yan-Tuan Wu, Zhi-Yong (2-Formyl-6-methoxyphenolato-κ(2) O (1),O (2))(perchlorato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | (2-Formyl-6-methoxyphenolato-κ(2)
O
(1),O
(2))(perchlorato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | (2-Formyl-6-methoxyphenolato-κ(2)
O
(1),O
(2))(perchlorato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | (2-Formyl-6-methoxyphenolato-κ(2)
O
(1),O
(2))(perchlorato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | (2-Formyl-6-methoxyphenolato-κ(2)
O
(1),O
(2))(perchlorato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | (2-Formyl-6-methoxyphenolato-κ(2)
O
(1),O
(2))(perchlorato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | (2-formyl-6-methoxyphenolato-κ(2)
o
(1),o
(2))(perchlorato-κo)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961256/ https://www.ncbi.nlm.nih.gov/pubmed/21202216 http://dx.doi.org/10.1107/S1600536808009975 |
work_keys_str_mv | AT dongfengying 2formyl6methoxyphenolatok2o1o2perchloratoko110phenanthrolinek2nncopperii AT sunyunming 2formyl6methoxyphenolatok2o1o2perchloratoko110phenanthrolinek2nncopperii AT liyantuan 2formyl6methoxyphenolatok2o1o2perchloratoko110phenanthrolinek2nncopperii AT wuzhiyong 2formyl6methoxyphenolatok2o1o2perchloratoko110phenanthrolinek2nncopperii |