4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)

The anion in the title salt, (C(7)H(11)N(2))[SnBr(2)(C(6)H(5))(3)], lies on a twofold rotation axis that passes through the metal atom as well as the C(ipso)—C(para) atoms of one of the aromatic rings. The metal center is five-coordinate in a trans-Br(2)SnC(3) trigonal bipyramidal geometry. The cati...

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Detalles Bibliográficos
Autores principales: Norhafiza, Ilyana, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961257/
https://www.ncbi.nlm.nih.gov/pubmed/21202246
http://dx.doi.org/10.1107/S1600536808011094
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author Norhafiza, Ilyana
Lo, Kong Mun
Ng, Seik Weng
author_facet Norhafiza, Ilyana
Lo, Kong Mun
Ng, Seik Weng
author_sort Norhafiza, Ilyana
collection PubMed
description The anion in the title salt, (C(7)H(11)N(2))[SnBr(2)(C(6)H(5))(3)], lies on a twofold rotation axis that passes through the metal atom as well as the C(ipso)—C(para) atoms of one of the aromatic rings. The metal center is five-coordinate in a trans-Br(2)SnC(3) trigonal bipyramidal geometry. The cation is disordered about a center of inversion.
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spelling pubmed-29612572010-12-30 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV) Norhafiza, Ilyana Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The anion in the title salt, (C(7)H(11)N(2))[SnBr(2)(C(6)H(5))(3)], lies on a twofold rotation axis that passes through the metal atom as well as the C(ipso)—C(para) atoms of one of the aromatic rings. The metal center is five-coordinate in a trans-Br(2)SnC(3) trigonal bipyramidal geometry. The cation is disordered about a center of inversion. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961257/ /pubmed/21202246 http://dx.doi.org/10.1107/S1600536808011094 Text en © Norhafiza et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Norhafiza, Ilyana
Lo, Kong Mun
Ng, Seik Weng
4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title_full 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title_fullStr 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title_full_unstemmed 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title_short 4-(Dimethylamino)pyridinium dibromidotriphenyl­stannate(IV)
title_sort 4-(dimethylamino)pyridinium dibromidotriphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961257/
https://www.ncbi.nlm.nih.gov/pubmed/21202246
http://dx.doi.org/10.1107/S1600536808011094
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AT lokongmun 4dimethylaminopyridiniumdibromidotriphenylstannateiv
AT ngseikweng 4dimethylaminopyridiniumdibromidotriphenylstannateiv

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