catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]

The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetra­hedral environment by the additional coordination of two water mol­ecules. The one-dimension...

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Detalles Bibliográficos
Autores principales: Shibahara, Takashi, Ogasahara, Shinobu, Sakane, Genta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961258/
https://www.ncbi.nlm.nih.gov/pubmed/21202165
http://dx.doi.org/10.1107/S1600536808007757
Descripción
Sumario:The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetra­hedral environment by the additional coordination of two water mol­ecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species.

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