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catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]

The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetra­hedral environment by the additional coordination of two water mol­ecules. The one-dimension...

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Detalles Bibliográficos
Autores principales: Shibahara, Takashi, Ogasahara, Shinobu, Sakane, Genta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961258/
https://www.ncbi.nlm.nih.gov/pubmed/21202165
http://dx.doi.org/10.1107/S1600536808007757
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author Shibahara, Takashi
Ogasahara, Shinobu
Sakane, Genta
author_facet Shibahara, Takashi
Ogasahara, Shinobu
Sakane, Genta
author_sort Shibahara, Takashi
collection PubMed
description The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetra­hedral environment by the additional coordination of two water mol­ecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species.
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spelling pubmed-29612582010-12-30 catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S] Shibahara, Takashi Ogasahara, Shinobu Sakane, Genta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetra­hedral environment by the additional coordination of two water mol­ecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961258/ /pubmed/21202165 http://dx.doi.org/10.1107/S1600536808007757 Text en © Shibahara et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shibahara, Takashi
Ogasahara, Shinobu
Sakane, Genta
catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title_full catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title_fullStr catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title_full_unstemmed catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title_short catena-Poly[[diaqua­zinc(II)]-μ-l-cystein­ato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis­[oxido­molybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
title_sort catena-poly[[diaqua­zinc(ii)]-μ-l-cystein­ato(2−)-κ(4) s:s,n,o-[di-μ-sulfido-bis­[oxido­molybdate(v)](mo—mo)]-μ-l-cysteinato(2−)-κ(4) s,n,o:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961258/
https://www.ncbi.nlm.nih.gov/pubmed/21202165
http://dx.doi.org/10.1107/S1600536808007757
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