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catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S]
The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimension...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961258/ https://www.ncbi.nlm.nih.gov/pubmed/21202165 http://dx.doi.org/10.1107/S1600536808007757 |
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author | Shibahara, Takashi Ogasahara, Shinobu Sakane, Genta |
author_facet | Shibahara, Takashi Ogasahara, Shinobu Sakane, Genta |
author_sort | Shibahara, Takashi |
collection | PubMed |
description | The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species. |
format | Text |
id | pubmed-2961258 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612582010-12-30 catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S] Shibahara, Takashi Ogasahara, Shinobu Sakane, Genta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)Zn(C(3)H(5)NO(2)S)(2)O(2)S(2)(H(2)O)(2)], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961258/ /pubmed/21202165 http://dx.doi.org/10.1107/S1600536808007757 Text en © Shibahara et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shibahara, Takashi Ogasahara, Shinobu Sakane, Genta catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4) S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4) S,N,O:S] |
title |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4)
S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4)
S,N,O:S] |
title_full |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4)
S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4)
S,N,O:S] |
title_fullStr |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4)
S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4)
S,N,O:S] |
title_full_unstemmed |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4)
S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4)
S,N,O:S] |
title_short |
catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ(4)
S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ(4)
S,N,O:S] |
title_sort | catena-poly[[diaquazinc(ii)]-μ-l-cysteinato(2−)-κ(4)
s:s,n,o-[di-μ-sulfido-bis[oxidomolybdate(v)](mo—mo)]-μ-l-cysteinato(2−)-κ(4)
s,n,o:s] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961258/ https://www.ncbi.nlm.nih.gov/pubmed/21202165 http://dx.doi.org/10.1107/S1600536808007757 |
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