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2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran
The title compound, C(16)H(12)O(5)S, was prepared by oxidation of 2-methyl-5,6-methylenedioxy-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 83.64 (4)° with the mean plane of the 5,6-(methylenedioxy)benzofuran fragment. The crysta...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961259/ https://www.ncbi.nlm.nih.gov/pubmed/21202337 http://dx.doi.org/10.1107/S160053680800980X |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | The title compound, C(16)H(12)O(5)S, was prepared by oxidation of 2-methyl-5,6-methylenedioxy-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 83.64 (4)° with the mean plane of the 5,6-(methylenedioxy)benzofuran fragment. The crystal structure is stabilized by C—H⋯π interactions between a benzene H atom of the 5,6-(methylenedioxy)benzofuran unit and the phenyl ring of the phenylsulfonyl substituent. Additionally, the crystal structure exhibits inter- and intramolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2961259 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612592010-12-30 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)O(5)S, was prepared by oxidation of 2-methyl-5,6-methylenedioxy-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 83.64 (4)° with the mean plane of the 5,6-(methylenedioxy)benzofuran fragment. The crystal structure is stabilized by C—H⋯π interactions between a benzene H atom of the 5,6-(methylenedioxy)benzofuran unit and the phenyl ring of the phenylsulfonyl substituent. Additionally, the crystal structure exhibits inter- and intramolecular C—H⋯O interactions. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961259/ /pubmed/21202337 http://dx.doi.org/10.1107/S160053680800980X Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title | 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title_full | 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title_fullStr | 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title_full_unstemmed | 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title_short | 2-Methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
title_sort | 2-methyl-5,6-methylenedioxy-3-phenylsulfonyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961259/ https://www.ncbi.nlm.nih.gov/pubmed/21202337 http://dx.doi.org/10.1107/S160053680800980X |
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