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Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/ https://www.ncbi.nlm.nih.gov/pubmed/21202240 http://dx.doi.org/10.1107/S1600536808010738 |
Sumario: | In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds. |
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