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Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]

In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[...

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Detalles Bibliográficos
Autores principales: Xu, Mao-Liang, Zhou, Rui, Wang, Ge-Yang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/
https://www.ncbi.nlm.nih.gov/pubmed/21202240
http://dx.doi.org/10.1107/S1600536808010738
Descripción
Sumario:In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds.