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Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]

In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[...

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Detalles Bibliográficos
Autores principales: Xu, Mao-Liang, Zhou, Rui, Wang, Ge-Yang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/
https://www.ncbi.nlm.nih.gov/pubmed/21202240
http://dx.doi.org/10.1107/S1600536808010738
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author Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
author_facet Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
author_sort Xu, Mao-Liang
collection PubMed
description In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds.
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spelling pubmed-29612602010-12-30 Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)] Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961260/ /pubmed/21202240 http://dx.doi.org/10.1107/S1600536808010738 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title_full Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title_fullStr Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title_full_unstemmed Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title_short Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis­[2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
title_sort poly[di-μ(5)-adipato-κ(4) o:o′:o′′:o′′′,o′′′-μ(4)-adipato-κ(4) o:o′:o′′:o′′′-bis­[2-phenyl-1h-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene-κ(2) n (7),n (8)]tricobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/
https://www.ncbi.nlm.nih.gov/pubmed/21202240
http://dx.doi.org/10.1107/S1600536808010738
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