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Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)]
In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/ https://www.ncbi.nlm.nih.gov/pubmed/21202240 http://dx.doi.org/10.1107/S1600536808010738 |
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author | Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng |
author_facet | Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng |
author_sort | Xu, Mao-Liang |
collection | PubMed |
description | In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961260 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612602010-12-30 Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)] Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2−)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961260/ /pubmed/21202240 http://dx.doi.org/10.1107/S1600536808010738 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng Poly[di-μ(5)-adipato-κ(4) O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4) O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8)]tricobalt(II)] |
title | Poly[di-μ(5)-adipato-κ(4)
O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4)
O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8)]tricobalt(II)] |
title_full | Poly[di-μ(5)-adipato-κ(4)
O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4)
O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8)]tricobalt(II)] |
title_fullStr | Poly[di-μ(5)-adipato-κ(4)
O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4)
O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8)]tricobalt(II)] |
title_full_unstemmed | Poly[di-μ(5)-adipato-κ(4)
O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4)
O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8)]tricobalt(II)] |
title_short | Poly[di-μ(5)-adipato-κ(4)
O:O′:O′′:O′′′,O′′′-μ(4)-adipato-κ(4)
O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8)]tricobalt(II)] |
title_sort | poly[di-μ(5)-adipato-κ(4)
o:o′:o′′:o′′′,o′′′-μ(4)-adipato-κ(4)
o:o′:o′′:o′′′-bis[2-phenyl-1h-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
n
(7),n
(8)]tricobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961260/ https://www.ncbi.nlm.nih.gov/pubmed/21202240 http://dx.doi.org/10.1107/S1600536808010738 |
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