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[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate)
In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the di...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961270/ https://www.ncbi.nlm.nih.gov/pubmed/21202183 http://dx.doi.org/10.1107/S1600536808008635 |
Sumario: | In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the distorted octahedron are occupied by a hydrazidate (NNH(2) (2−)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3. |
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