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[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate)
In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the di...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961270/ https://www.ncbi.nlm.nih.gov/pubmed/21202183 http://dx.doi.org/10.1107/S1600536808008635 |
| _version_ | 1782188942396751872 |
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| author | Stephan, Gerald Näther, Christian Tuczek, Felix |
| author_facet | Stephan, Gerald Näther, Christian Tuczek, Felix |
| author_sort | Stephan, Gerald |
| collection | PubMed |
| description | In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the distorted octahedron are occupied by a hydrazidate (NNH(2) (2−)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3. |
| format | Text |
| id | pubmed-2961270 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29612702010-12-30 [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) Stephan, Gerald Näther, Christian Tuczek, Felix Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the distorted octahedron are occupied by a hydrazidate (NNH(2) (2−)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961270/ /pubmed/21202183 http://dx.doi.org/10.1107/S1600536808008635 Text en © Stephan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Stephan, Gerald Näther, Christian Tuczek, Felix [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title | [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title_full | [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title_fullStr | [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title_full_unstemmed | [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title_short | [1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) |
| title_sort | [1,2-bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(iv) bis(tetrafluoridoborate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961270/ https://www.ncbi.nlm.nih.gov/pubmed/21202183 http://dx.doi.org/10.1107/S1600536808008635 |
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