Tetra­aqua­bis(biuret-κ(2) O,O′)yttrium(III) trichloride

In the title compound, [Y(C(2)H(5)N(3)O(2))(2)(H(2)O)(4)]Cl(3), the Y(3+) ion (site symmetry 2) is bonded to eight O atoms (arising from two O,O′-bidentate biuret mol­ecules and four water mol­ecules) in a distorted square-anti­prismatic arrangement. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bo...

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Detalles Bibliográficos
Autor principal: Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961277/
https://www.ncbi.nlm.nih.gov/pubmed/21202174
http://dx.doi.org/10.1107/S1600536808008659
Descripción
Sumario:In the title compound, [Y(C(2)H(5)N(3)O(2))(2)(H(2)O)(4)]Cl(3), the Y(3+) ion (site symmetry 2) is bonded to eight O atoms (arising from two O,O′-bidentate biuret mol­ecules and four water mol­ecules) in a distorted square-anti­prismatic arrangement. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds help to establish the packing, leading to a three-dimensional network. One of the chloride ions has site symmetry 2.

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