Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate

The crystal structure of the title compound, [C(NH(2))(3)](6)[Mo(7)O(24)]·H(2)O, previously determined at room temperature in the monoclinic space group C2/c from Weissenberg techniques [Don & Weakley (1981 ▶). Acta Cryst. B37, 451–453], has been redetermined from low-temperature single-crystal...

Descripción completa

Detalles Bibliográficos
Autores principales: Reinoso, Santiago, Dickman, Michael H., Praetorius, Antonia, Kortz*, Ulrich
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961279/
https://www.ncbi.nlm.nih.gov/pubmed/21202171
http://dx.doi.org/10.1107/S1600536808008234
_version_ 1782188944639655936
author Reinoso, Santiago
Dickman, Michael H.
Praetorius, Antonia
Kortz*, Ulrich
author_facet Reinoso, Santiago
Dickman, Michael H.
Praetorius, Antonia
Kortz*, Ulrich
author_sort Reinoso, Santiago
collection PubMed
description The crystal structure of the title compound, [C(NH(2))(3)](6)[Mo(7)O(24)]·H(2)O, previously determined at room temperature in the monoclinic space group C2/c from Weissenberg techniques [Don & Weakley (1981 ▶). Acta Cryst. B37, 451–453], has been redetermined from low-temperature single-crystal data in the monoclinic space group P2(1)/c. The asymmetric unit contains one hepta­molybdate anion, six guanidinium cations and one water mol­ecule of hydration. The anions and cations are linked by an extensive network of N—H⋯O hydrogen bonds.
format Text
id pubmed-2961279
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29612792010-12-30 Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate Reinoso, Santiago Dickman, Michael H. Praetorius, Antonia Kortz*, Ulrich Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [C(NH(2))(3)](6)[Mo(7)O(24)]·H(2)O, previously determined at room temperature in the monoclinic space group C2/c from Weissenberg techniques [Don & Weakley (1981 ▶). Acta Cryst. B37, 451–453], has been redetermined from low-temperature single-crystal data in the monoclinic space group P2(1)/c. The asymmetric unit contains one hepta­molybdate anion, six guanidinium cations and one water mol­ecule of hydration. The anions and cations are linked by an extensive network of N—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961279/ /pubmed/21202171 http://dx.doi.org/10.1107/S1600536808008234 Text en © Reinoso et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reinoso, Santiago
Dickman, Michael H.
Praetorius, Antonia
Kortz*, Ulrich
Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title_full Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title_fullStr Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title_full_unstemmed Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title_short Low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
title_sort low-temperature phase of hexaguanidinium hepta­molybdate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961279/
https://www.ncbi.nlm.nih.gov/pubmed/21202171
http://dx.doi.org/10.1107/S1600536808008234
work_keys_str_mv AT reinososantiago lowtemperaturephaseofhexaguanidiniumheptamolybdatemonohydrate
AT dickmanmichaelh lowtemperaturephaseofhexaguanidiniumheptamolybdatemonohydrate
AT praetoriusantonia lowtemperaturephaseofhexaguanidiniumheptamolybdatemonohydrate
AT kortzulrich lowtemperaturephaseofhexaguanidiniumheptamolybdatemonohydrate

Ejemplares similares