Tetrakis(thiourea-κS)palladium(II) dithio­cyanate

The title compound, [Pd(CH(4)N(2)S)(4)](SCN)(2), consists of complex [Pd(TU)(4)](2+) [TU = thio­urea, SC(NH(2))(2)] cations and thio­cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The co...

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Detalles Bibliográficos
Autores principales: Nadeem, Shafqat, Khawar Rauf, M., Ebihara, Masahiro, Tirmizi, Syed Ahmed, Ahmad, Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961283/
https://www.ncbi.nlm.nih.gov/pubmed/21202232
http://dx.doi.org/10.1107/S160053680801088X
Descripción
Sumario:The title compound, [Pd(CH(4)N(2)S)(4)](SCN)(2), consists of complex [Pd(TU)(4)](2+) [TU = thio­urea, SC(NH(2))(2)] cations and thio­cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thio­cyanate ions via N—H⋯N [2.922 (3)–3.056 (3) Å] and N—H⋯S [3.369 (2)–3.645 (2) Å] hydrogen bonds.

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