Tetrakis(thiourea-κS)palladium(II) dithio­cyanate

The title compound, [Pd(CH(4)N(2)S)(4)](SCN)(2), consists of complex [Pd(TU)(4)](2+) [TU = thio­urea, SC(NH(2))(2)] cations and thio­cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The co...

Descripción completa

Detalles Bibliográficos
Autores principales: Nadeem, Shafqat, Khawar Rauf, M., Ebihara, Masahiro, Tirmizi, Syed Ahmed, Ahmad, Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961283/
https://www.ncbi.nlm.nih.gov/pubmed/21202232
http://dx.doi.org/10.1107/S160053680801088X
_version_ 1782188945594908672
author Nadeem, Shafqat
Khawar Rauf, M.
Ebihara, Masahiro
Tirmizi, Syed Ahmed
Ahmad, Saeed
author_facet Nadeem, Shafqat
Khawar Rauf, M.
Ebihara, Masahiro
Tirmizi, Syed Ahmed
Ahmad, Saeed
author_sort Nadeem, Shafqat
collection PubMed
description The title compound, [Pd(CH(4)N(2)S)(4)](SCN)(2), consists of complex [Pd(TU)(4)](2+) [TU = thio­urea, SC(NH(2))(2)] cations and thio­cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thio­cyanate ions via N—H⋯N [2.922 (3)–3.056 (3) Å] and N—H⋯S [3.369 (2)–3.645 (2) Å] hydrogen bonds.
format Text
id pubmed-2961283
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29612832010-12-30 Tetrakis(thiourea-κS)palladium(II) dithio­cyanate Nadeem, Shafqat Khawar Rauf, M. Ebihara, Masahiro Tirmizi, Syed Ahmed Ahmad, Saeed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(CH(4)N(2)S)(4)](SCN)(2), consists of complex [Pd(TU)(4)](2+) [TU = thio­urea, SC(NH(2))(2)] cations and thio­cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thio­cyanate ions via N—H⋯N [2.922 (3)–3.056 (3) Å] and N—H⋯S [3.369 (2)–3.645 (2) Å] hydrogen bonds. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961283/ /pubmed/21202232 http://dx.doi.org/10.1107/S160053680801088X Text en © Nadeem et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nadeem, Shafqat
Khawar Rauf, M.
Ebihara, Masahiro
Tirmizi, Syed Ahmed
Ahmad, Saeed
Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title_full Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title_fullStr Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title_full_unstemmed Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title_short Tetrakis(thiourea-κS)palladium(II) dithio­cyanate
title_sort tetrakis(thiourea-κs)palladium(ii) dithio­cyanate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961283/
https://www.ncbi.nlm.nih.gov/pubmed/21202232
http://dx.doi.org/10.1107/S160053680801088X
work_keys_str_mv AT nadeemshafqat tetrakisthioureakspalladiumiidithiocyanate
AT khawarraufm tetrakisthioureakspalladiumiidithiocyanate
AT ebiharamasahiro tetrakisthioureakspalladiumiidithiocyanate
AT tirmizisyedahmed tetrakisthioureakspalladiumiidithiocyanate
AT ahmadsaeed tetrakisthioureakspalladiumiidithiocyanate

Ejemplares similares