Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)

The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (−) anions which are arranged in alternatin...

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Detalles Bibliográficos
Autores principales: Walbaum, Christine, Pantenburg, Ingo, Meyer, Gerd
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961288/
https://www.ncbi.nlm.nih.gov/pubmed/21202264
http://dx.doi.org/10.1107/S1600536808012373
Descripción
Sumario:The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (−) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

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