Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)

The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (−) anions which are arranged in alternatin...

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Detalles Bibliográficos
Autores principales: Walbaum, Christine, Pantenburg, Ingo, Meyer, Gerd
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961288/
https://www.ncbi.nlm.nih.gov/pubmed/21202264
http://dx.doi.org/10.1107/S1600536808012373
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author Walbaum, Christine
Pantenburg, Ingo
Meyer, Gerd
author_facet Walbaum, Christine
Pantenburg, Ingo
Meyer, Gerd
author_sort Walbaum, Christine
collection PubMed
description The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (−) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.
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spelling pubmed-29612882010-12-30 Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide) Walbaum, Christine Pantenburg, Ingo Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (−) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961288/ /pubmed/21202264 http://dx.doi.org/10.1107/S1600536808012373 Text en © Walbaum et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Walbaum, Christine
Pantenburg, Ingo
Meyer, Gerd
Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title_full Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title_fullStr Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title_full_unstemmed Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title_short Bis(benzo-15-crown-5-κ(5) O)strontium bis­(triiodide)
title_sort bis(benzo-15-crown-5-κ(5) o)strontium bis­(triiodide)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961288/
https://www.ncbi.nlm.nih.gov/pubmed/21202264
http://dx.doi.org/10.1107/S1600536808012373
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AT pantenburgingo bisbenzo15crown5k5ostrontiumbistriiodide
AT meyergerd bisbenzo15crown5k5ostrontiumbistriiodide

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