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(2,2′-Bipyridine-κ(2) N,N′)[N-(2-oxido-1-naphthyl­idene)threoninato-κ(3) O (1),N,O (2)]copper(II)

In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2′-bipyridine...

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Detalles Bibliográficos
Autores principales: Qiu, Zhanglei, Li, Lianzhi, Liu, Yan, Xu, Tao, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961289/
https://www.ncbi.nlm.nih.gov/pubmed/21202263
http://dx.doi.org/10.1107/S1600536808012191
Descripción
Sumario:In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter­molecular O—H⋯O and C—H⋯O hydrogen bonds leads to a two-dimensional network.