Cargando…
(2,2′-Bipyridine-κ(2) N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3) O (1),N,O (2)]copper(II)
In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydroxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2′-bipyridine...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961289/ https://www.ncbi.nlm.nih.gov/pubmed/21202263 http://dx.doi.org/10.1107/S1600536808012191 |
| _version_ | 1782188947018874880 |
|---|---|
| author | Qiu, Zhanglei Li, Lianzhi Liu, Yan Xu, Tao Wang, Daqi |
| author_facet | Qiu, Zhanglei Li, Lianzhi Liu, Yan Xu, Tao Wang, Daqi |
| author_sort | Qiu, Zhanglei |
| collection | PubMed |
| description | In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydroxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of intermolecular O—H⋯O and C—H⋯O hydrogen bonds leads to a two-dimensional network. |
| format | Text |
| id | pubmed-2961289 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29612892010-12-30 (2,2′-Bipyridine-κ(2) N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3) O (1),N,O (2)]copper(II) Qiu, Zhanglei Li, Lianzhi Liu, Yan Xu, Tao Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydroxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of intermolecular O—H⋯O and C—H⋯O hydrogen bonds leads to a two-dimensional network. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961289/ /pubmed/21202263 http://dx.doi.org/10.1107/S1600536808012191 Text en © Qiu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Qiu, Zhanglei Li, Lianzhi Liu, Yan Xu, Tao Wang, Daqi (2,2′-Bipyridine-κ(2) N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3) O (1),N,O (2)]copper(II) |
| title | (2,2′-Bipyridine-κ(2)
N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3)
O
(1),N,O
(2)]copper(II) |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3)
O
(1),N,O
(2)]copper(II) |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3)
O
(1),N,O
(2)]copper(II) |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3)
O
(1),N,O
(2)]copper(II) |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ(3)
O
(1),N,O
(2)]copper(II) |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)[n-(2-oxido-1-naphthylidene)threoninato-κ(3)
o
(1),n,o
(2)]copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961289/ https://www.ncbi.nlm.nih.gov/pubmed/21202263 http://dx.doi.org/10.1107/S1600536808012191 |
| work_keys_str_mv | AT qiuzhanglei 22bipyridinek2nnn2oxido1naphthylidenethreoninatok3o1no2copperii AT lilianzhi 22bipyridinek2nnn2oxido1naphthylidenethreoninatok3o1no2copperii AT liuyan 22bipyridinek2nnn2oxido1naphthylidenethreoninatok3o1no2copperii AT xutao 22bipyridinek2nnn2oxido1naphthylidenethreoninatok3o1no2copperii AT wangdaqi 22bipyridinek2nnn2oxido1naphthylidenethreoninatok3o1no2copperii |