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3-(4-Chlorophenylsulfonyl)-2-methylnaphtho[1,2-b]furan
The title compound, C(19)H(13)ClO(3)S, was prepared by the oxidation of 3-(4-chlorophenylsulfanyl)-2-methylnaphtho[1,2-b]furan with 3-chloroperoxybenzoic acid. The 4-chlorophenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is st...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961290/ https://www.ncbi.nlm.nih.gov/pubmed/21202325 http://dx.doi.org/10.1107/S1600536808009215 |
Sumario: | The title compound, C(19)H(13)ClO(3)S, was prepared by the oxidation of 3-(4-chlorophenylsulfanyl)-2-methylnaphtho[1,2-b]furan with 3-chloroperoxybenzoic acid. The 4-chlorophenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.635 (3) Å], and by C—H⋯π interactions between a methyl H atom and the furan ring of an adjacent molecule. In addition, the crystal structure exhibits intermolecular C—H⋯O interactions. |
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