3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan

The title compound, C(19)H(13)ClO(3)S, was prepared by the oxidation of 3-(4-chloro­phenyl­sulfan­yl)-2-methyl­naphtho[1,2-b]furan with 3-chloro­peroxy­benzoic acid. The 4-chloro­phenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is st...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961290/
https://www.ncbi.nlm.nih.gov/pubmed/21202325
http://dx.doi.org/10.1107/S1600536808009215
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The title compound, C(19)H(13)ClO(3)S, was prepared by the oxidation of 3-(4-chloro­phenyl­sulfan­yl)-2-methyl­naphtho[1,2-b]furan with 3-chloro­peroxy­benzoic acid. The 4-chloro­phenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.635 (3) Å], and by C—H⋯π inter­actions between a methyl H atom and the furan ring of an adjacent mol­ecule. In addition, the crystal structure exhibits inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29612902010-12-30 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(13)ClO(3)S, was prepared by the oxidation of 3-(4-chloro­phenyl­sulfan­yl)-2-methyl­naphtho[1,2-b]furan with 3-chloro­peroxy­benzoic acid. The 4-chloro­phenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.635 (3) Å], and by C—H⋯π inter­actions between a methyl H atom and the furan ring of an adjacent mol­ecule. In addition, the crystal structure exhibits inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961290/ /pubmed/21202325 http://dx.doi.org/10.1107/S1600536808009215 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title_full 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title_fullStr 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title_full_unstemmed 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title_short 3-(4-Chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
title_sort 3-(4-chloro­phenyl­sulfon­yl)-2-methyl­naphtho[1,2-b]furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961290/
https://www.ncbi.nlm.nih.gov/pubmed/21202325
http://dx.doi.org/10.1107/S1600536808009215
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AT leeuk 34chlorophenylsulfonyl2methylnaphtho12bfuran

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