4-Anilino-1-benzyl­piperidine-4-carbo­nitrile

The title mol­ecule, C(19)H(21)N(3), an important precursor in the synthesis of porphyrin–fentanyl conjugates, has its piperidine ring in the chair conformation, with endocyclic torsion-angle magnitudes in the range 53.26 (8)–60.63 (9)°. The C N group is axial, while the CH(2)Ph and NHPh groups are...

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Detalles Bibliográficos
Autores principales: Allam, Kiran K., Fronczek, Frank R., Vicente, M. Graça H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961292/
https://www.ncbi.nlm.nih.gov/pubmed/21202327
http://dx.doi.org/10.1107/S1600536808009136
Descripción
Sumario:The title mol­ecule, C(19)H(21)N(3), an important precursor in the synthesis of porphyrin–fentanyl conjugates, has its piperidine ring in the chair conformation, with endocyclic torsion-angle magnitudes in the range 53.26 (8)–60.63 (9)°. The C N group is axial, while the CH(2)Ph and NHPh groups are equatorial. The NH group does not engage in strong hydrogen bonding, but forms an inter­molecular N—H⋯N inter­action.

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