4-Anilino-1-benzyl­piperidine-4-carbo­nitrile

The title mol­ecule, C(19)H(21)N(3), an important precursor in the synthesis of porphyrin–fentanyl conjugates, has its piperidine ring in the chair conformation, with endocyclic torsion-angle magnitudes in the range 53.26 (8)–60.63 (9)°. The C N group is axial, while the CH(2)Ph and NHPh groups are...

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Detalles Bibliográficos
Autores principales: Allam, Kiran K., Fronczek, Frank R., Vicente, M. Graça H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961292/
https://www.ncbi.nlm.nih.gov/pubmed/21202327
http://dx.doi.org/10.1107/S1600536808009136
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author Allam, Kiran K.
Fronczek, Frank R.
Vicente, M. Graça H.
author_facet Allam, Kiran K.
Fronczek, Frank R.
Vicente, M. Graça H.
author_sort Allam, Kiran K.
collection PubMed
description The title mol­ecule, C(19)H(21)N(3), an important precursor in the synthesis of porphyrin–fentanyl conjugates, has its piperidine ring in the chair conformation, with endocyclic torsion-angle magnitudes in the range 53.26 (8)–60.63 (9)°. The C N group is axial, while the CH(2)Ph and NHPh groups are equatorial. The NH group does not engage in strong hydrogen bonding, but forms an inter­molecular N—H⋯N inter­action.
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spelling pubmed-29612922010-12-30 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile Allam, Kiran K. Fronczek, Frank R. Vicente, M. Graça H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(19)H(21)N(3), an important precursor in the synthesis of porphyrin–fentanyl conjugates, has its piperidine ring in the chair conformation, with endocyclic torsion-angle magnitudes in the range 53.26 (8)–60.63 (9)°. The C N group is axial, while the CH(2)Ph and NHPh groups are equatorial. The NH group does not engage in strong hydrogen bonding, but forms an inter­molecular N—H⋯N inter­action. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961292/ /pubmed/21202327 http://dx.doi.org/10.1107/S1600536808009136 Text en © Allam et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Allam, Kiran K.
Fronczek, Frank R.
Vicente, M. Graça H.
4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title_full 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title_fullStr 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title_full_unstemmed 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title_short 4-Anilino-1-benzyl­piperidine-4-carbo­nitrile
title_sort 4-anilino-1-benzyl­piperidine-4-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961292/
https://www.ncbi.nlm.nih.gov/pubmed/21202327
http://dx.doi.org/10.1107/S1600536808009136
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AT fronczekfrankr 4anilino1benzylpiperidine4carbonitrile
AT vicentemgracah 4anilino1benzylpiperidine4carbonitrile

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