(7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate

In the title compound, C(20)H(32)N(+)·C(7)H(7)O(3)S(−), the configurations of the two chiral centers observed in the protonated cation are consistent with previous reports. In the crystal structure, weak inter­molecular N—H⋯O hydrogen bonds link ions into chains which develop along the a axis. The i...

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Detalles Bibliográficos
Autores principales: Li, Yong, Zeng, Tao, Huang, Dao-zhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961293/
https://www.ncbi.nlm.nih.gov/pubmed/21202358
http://dx.doi.org/10.1107/S1600536808010210
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author Li, Yong
Zeng, Tao
Huang, Dao-zhan
author_facet Li, Yong
Zeng, Tao
Huang, Dao-zhan
author_sort Li, Yong
collection PubMed
description In the title compound, C(20)H(32)N(+)·C(7)H(7)O(3)S(−), the configurations of the two chiral centers observed in the protonated cation are consistent with previous reports. In the crystal structure, weak inter­molecular N—H⋯O hydrogen bonds link ions into chains which develop along the a axis. The isopropyl group and four CH groups of the attached benzene ring are disordered approximately equally over two positions.
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spelling pubmed-29612932010-12-30 (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate Li, Yong Zeng, Tao Huang, Dao-zhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(32)N(+)·C(7)H(7)O(3)S(−), the configurations of the two chiral centers observed in the protonated cation are consistent with previous reports. In the crystal structure, weak inter­molecular N—H⋯O hydrogen bonds link ions into chains which develop along the a axis. The isopropyl group and four CH groups of the attached benzene ring are disordered approximately equally over two positions. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961293/ /pubmed/21202358 http://dx.doi.org/10.1107/S1600536808010210 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Yong
Zeng, Tao
Huang, Dao-zhan
(7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title_full (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title_fullStr (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title_full_unstemmed (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title_short (7-Isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
title_sort (7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,-9,10,10a-octa­hydro­phenanthren-1-yl)­methanaminium 4-toluene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961293/
https://www.ncbi.nlm.nih.gov/pubmed/21202358
http://dx.doi.org/10.1107/S1600536808010210
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AT zengtao 7isopropyl14adimethyl12344a91010aoctahydrophenanthren1ylmethanaminium4toluenesulfonate
AT huangdaozhan 7isopropyl14adimethyl12344a91010aoctahydrophenanthren1ylmethanaminium4toluenesulfonate

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