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3-(3-Chloropropyl)-7,8-dimethoxy-1H-3-benzazepin-2(3H)-one at 125 K
In the title compound, C(15)H(18)ClNO(3), the seven-membered ring has a mirror plane passing through the methylene C atom and bisecting the C=C bond. It adopts a bent conformation, intermediate between the boat and chair forms. Both methoxy groups are coplanar with the attached benzene ring [C—C...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961294/ https://www.ncbi.nlm.nih.gov/pubmed/21202388 http://dx.doi.org/10.1107/S1600536808011264 |
Sumario: | In the title compound, C(15)H(18)ClNO(3), the seven-membered ring has a mirror plane passing through the methylene C atom and bisecting the C=C bond. It adopts a bent conformation, intermediate between the boat and chair forms. Both methoxy groups are coplanar with the attached benzene ring [C—C—O—C = −0.5 (3) and 2.2 (3)°]. In the crystal structure, inversion-related molecules are linked via C—H⋯O hydrogen bonds and π–π interactions involving the benzene ring [centroid–centroid distance = 3.6393 (12)Å]. |
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